Questions

Here all the given compounds have both ionic and covalent bonds.

NaNO3 - In Sodium nitrate, Nitrate is covalently bonded as nitrogen is bonded with 3 oxygen atoms. And this nitrate is ionically bonded with sodium.

CaSO4 - In Calcium sulphate, sulphate is covalently bonded as sulphur is bonded with 4 oxygen atoms. And this sulphate is ionically bonded with calcium.

NH4Cl - In Ammonium chloride, ammonium is covalently bonded as nitrogen is bonded with 4 hydrogen atoms. And this ammonium is ionically bonded with chlorine.

Refractorymeans unmanageablewhich is nearly opposite to manageable.Refreshing means revivifyingBurdensome means troublesomePrivileged means advantage

Since they can do 19 programs in 19 hours, Then 52 programs in 52 hours respectively.
And a 15 min interval
Total time they take to do 52 programs is 52 hours 15 minutes.

It is Blackboard or Chalkboard which is Black when clean, and as you write on it with white chalk it becomes dirty in White color.